Ammonium nitrate

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Ammonium Nitrate

Ammonium nitrate is a chemical compound with the formula NH_NO_. It is a white crystalline solid and is highly soluble in water. It is predominantly used in agriculture as a high-nitrogen fertilizer. The compound is also employed in explosives, particularly in mining and construction, due to its oxidizing properties.

Chemical Properties

Ammonium nitrate is composed of ammonium ions (NH__) and nitrate ions (NO__). It is a salt of ammonia and nitric acid. The compound is hygroscopic, meaning it readily absorbs moisture from the air, which can lead to caking and difficulty in handling.

Reactions

Ammonium nitrate decomposes explosively when heated to temperatures above 210 °C. The decomposition reaction is exothermic and can be represented as:

2 NH_NO_ _ 2 N_ + O_ + 4 H_O

This reaction releases nitrogen, oxygen, and water vapor, and is the basis for its use in explosives.

Uses

Fertilizer

Ammonium nitrate is widely used as a fertilizer due to its high nitrogen content, which is essential for plant growth. It is often applied in granular form and is valued for its ability to provide a quick release of nitrogen to plants.

Explosives

In the explosives industry, ammonium nitrate is used as an oxidizing agent in the production of ANFO (Ammonium Nitrate Fuel Oil), a widely used bulk explosive. It is favored for its stability and cost-effectiveness.

Safety and Handling

Ammonium nitrate is classified as an oxidizer and can enhance the combustion of other materials. It must be stored in a cool, dry place away from organic materials and sources of heat. The compound is subject to strict regulations due to its potential for misuse in improvised explosive devices.

Environmental Impact

The use of ammonium nitrate as a fertilizer can lead to environmental concerns such as eutrophication, where excess nutrients run off into water bodies, causing algal blooms and oxygen depletion. Proper management and application techniques are essential to minimize these impacts.

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Contributors: Prab R. Tumpati, MD