Polymerization

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Polymerization

Polymerization (pronunciation: /ˌpɒlɪməraɪˈzeɪʃən/) is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks.

Etymology

The term "polymerization" comes from the Greek words "poly" meaning many, and "meros" meaning parts. It was first used in the mid-19th century to describe the process of creating a polymer from monomers.

Types of Polymerization

There are two basic types of polymerization: addition polymerization and condensation polymerization.

  • Addition Polymerization: In addition polymerization, the monomers add together to form a polymer without the loss of any other atoms. This type of polymerization often involves the formation of a free radical to initiate the reaction.
  • Condensation Polymerization: In condensation polymerization, the monomers join together to form a polymer and a small molecule such as water or methanol is eliminated.

Related Terms

  • Monomer: A molecule that can join together with other molecules to form a polymer.
  • Polymer: A large molecule composed of many repeated subunits, known as monomers.
  • Free Radical: A molecule with an unpaired electron, which is highly reactive.
  • Addition Polymerization: A type of polymerization in which the monomers simply add together to form a polymer, with no other products.
  • Condensation Polymerization: A type of polymerization in which the monomers join together to form a polymer and a small molecule is eliminated.

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