Iron(II) sulfate: Difference between revisions

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{{DISPLAYTITLE:Iron(II) sulfate}}
{{DISPLAYTITLE:Iron(II) sulfate}}


[[File:Fe(H2O)6SO4.png|thumb|right|Structural formula of Iron(II) sulfate]]
[[File:Fe(H2O)6SO4.png|thumb|right|Structure of the hexaaquairon(II) sulfate complex]]


'''Iron(II) sulfate''', also known as '''ferrous sulfate''', is a chemical compound with the formula FeSO₄. It is commonly encountered as the heptahydrate, FeSO₄·7H₂O, which is a blue-green crystalline solid. Iron(II) sulfate is used in various applications, including as a precursor to other iron compounds, in water treatment, and as a nutritional supplement.
'''Iron(II) sulfate''', also known as '''ferrous sulfate''', is a chemical compound with the formula FeSO₄. It is commonly encountered as the heptahydrate, FeSO₄·7H₂O, which is a blue-green crystalline solid. This compound is used in various applications, including as a precursor to other iron compounds, in water treatment, and as a nutritional supplement.


==Chemical Properties==
==Chemical Properties==
Iron(II) sulfate is a [[sulfate]] salt of [[iron]] in the +2 oxidation state. The compound is typically found in its heptahydrate form, which is known as green vitriol or copperas. The anhydrous form is a white crystalline solid, while the heptahydrate is blue-green.
Iron(II) sulfate is a [[sulfate]] salt of [[iron]] in the +2 oxidation state. The anhydrous form is a white crystalline solid, while the heptahydrate form is blue-green. The compound is soluble in water, and its solutions are acidic due to hydrolysis.


[[File:Iron(II)-sulfate-heptahydrate-3D-balls.tiff|thumb|left|3D model of Iron(II) sulfate heptahydrate]]
[[File:Iron(II)-sulfate-heptahydrate-3D-balls.tiff|thumb|left|3D model of iron(II) sulfate heptahydrate]]


===Hydration States===
===Hydration States===
Iron(II) sulfate can exist in several hydrated forms, including the monohydrate, tetrahydrate, pentahydrate, and heptahydrate. The heptahydrate is the most common form and is often used in industrial applications. The hydration state affects the compound's solubility and stability.
Iron(II) sulfate exists in several hydrated forms, the most common being the heptahydrate. Other hydrates include the monohydrate and tetrahydrate. The heptahydrate loses water upon heating, eventually forming the anhydrous form.
 
===Reactivity===
Iron(II) sulfate is soluble in water and forms a pale green solution. It is a reducing agent and can be oxidized to iron(III) sulfate in the presence of oxidizing agents. The compound decomposes upon heating, releasing sulfur dioxide and leaving behind iron(III) oxide.


==Production==
==Production==
Iron(II) sulfate is produced as a byproduct of the steel pickling process, where iron is treated with sulfuric acid. It can also be synthesized by reacting iron with sulfuric acid:
Iron(II) sulfate is produced by treating iron with sulfuric acid, often as a byproduct of the pickling of steel:


:Fe + H₂SO₄ → FeSO₄ + H₂
:Fe + H₂SO₄ → FeSO₄ + H₂


This reaction produces hydrogen gas and iron(II) sulfate.
It can also be obtained by the oxidation of pyrite (iron sulfide) or by the reaction of iron with copper(II) sulfate.


==Applications==
==Applications==


===Industrial Uses===
===Industrial Uses===
Iron(II) sulfate is used in the production of [[iron(III) oxide]] pigments, as a reducing agent in the treatment of [[chromate]]-containing effluents, and in the manufacture of other iron compounds.
Iron(II) sulfate is used in the manufacture of [[iron(III) oxide]] pigments, as a reducing agent in the treatment of [[chromate]]-containing effluents, and in the production of [[iron(III) sulfate]].
 
[[File:Iron(II)-sulfate-heptahydrate-sample.jpg|thumb|right|Sample of Iron(II) sulfate heptahydrate]]


===Water Treatment===
[[File:Iron(II)-sulfate-heptahydrate-sample.jpg|thumb|right|Sample of iron(II) sulfate heptahydrate]]
In water treatment, iron(II) sulfate is used as a coagulant to remove impurities and as a flocculant to improve the sedimentation of suspended solids. It is also used to treat [[sewage]] and industrial waste.


===Agriculture===
===Agriculture===
Iron(II) sulfate is used as a soil amendment to correct iron chlorosis, a condition caused by iron deficiency in plants. It is also used as a moss killer in lawns and gardens.
In agriculture, iron(II) sulfate is used as a soil amendment for lowering the pH of a high alkaline soil so that plants can access the soil's nutrients. It is also used to treat iron chlorosis, a condition in which leaves produce insufficient chlorophyll.


===Medicine===
===Medical Uses===
In medicine, iron(II) sulfate is used as an iron supplement to treat iron-deficiency anemia. It is available in various forms, including tablets and liquid solutions.
Iron(II) sulfate is used as a [[dietary supplement]] to treat iron-deficiency anemia. It is available in various forms, including tablets and liquid solutions.


==Safety==
==Safety==
Iron(II) sulfate is generally considered safe when used as directed. However, it can be harmful if ingested in large quantities, leading to iron poisoning. It should be handled with care to avoid skin and eye irritation.
Iron(II) sulfate is generally considered safe when used as directed. However, it can be toxic in large amounts, particularly to children. It should be stored out of reach of children and handled with care to avoid ingestion.


[[File:Síran_železnatý.PNG|thumb|left|Iron(II) sulfate crystals]]
[[File:Síran_železnatý.PNG|thumb|left|Iron(II) sulfate crystals]]
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==Related Compounds==
==Related Compounds==
* [[Iron(III) sulfate]]
* [[Iron(III) sulfate]]
* [[Iron(II) chloride]]
* [[Copper(II) sulfate]]
* [[Iron(III) chloride]]
* [[Zinc sulfate]]


==Related Pages==
==Related Pages==
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[[Category:Iron compounds]]
[[Category:Iron compounds]]
[[Category:Sulfates]]
[[Category:Sulfates]]
[[Category:Reducing agents]]
[[Category:Food additives]]

Latest revision as of 22:59, 5 March 2025

Chemical compound



Structure of the hexaaquairon(II) sulfate complex

Iron(II) sulfate, also known as ferrous sulfate, is a chemical compound with the formula FeSO₄. It is commonly encountered as the heptahydrate, FeSO₄·7H₂O, which is a blue-green crystalline solid. This compound is used in various applications, including as a precursor to other iron compounds, in water treatment, and as a nutritional supplement.

Chemical Properties[edit]

Iron(II) sulfate is a sulfate salt of iron in the +2 oxidation state. The anhydrous form is a white crystalline solid, while the heptahydrate form is blue-green. The compound is soluble in water, and its solutions are acidic due to hydrolysis.

3D model of iron(II) sulfate heptahydrate

Hydration States[edit]

Iron(II) sulfate exists in several hydrated forms, the most common being the heptahydrate. Other hydrates include the monohydrate and tetrahydrate. The heptahydrate loses water upon heating, eventually forming the anhydrous form.

Production[edit]

Iron(II) sulfate is produced by treating iron with sulfuric acid, often as a byproduct of the pickling of steel:

Fe + H₂SO₄ → FeSO₄ + H₂

It can also be obtained by the oxidation of pyrite (iron sulfide) or by the reaction of iron with copper(II) sulfate.

Applications[edit]

Industrial Uses[edit]

Iron(II) sulfate is used in the manufacture of iron(III) oxide pigments, as a reducing agent in the treatment of chromate-containing effluents, and in the production of iron(III) sulfate.

Sample of iron(II) sulfate heptahydrate

Agriculture[edit]

In agriculture, iron(II) sulfate is used as a soil amendment for lowering the pH of a high alkaline soil so that plants can access the soil's nutrients. It is also used to treat iron chlorosis, a condition in which leaves produce insufficient chlorophyll.

Medical Uses[edit]

Iron(II) sulfate is used as a dietary supplement to treat iron-deficiency anemia. It is available in various forms, including tablets and liquid solutions.

Safety[edit]

Iron(II) sulfate is generally considered safe when used as directed. However, it can be toxic in large amounts, particularly to children. It should be stored out of reach of children and handled with care to avoid ingestion.

Iron(II) sulfate crystals

Related Compounds[edit]

Related Pages[edit]