Tetrasodium pyrophosphate

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Chemical compound used in food and industrial applications


Tetrasodium pyrophosphate, also known as sodium pyrophosphate or TSPP, is an inorganic compound with the formula Na4P2O7. It is a white, water-soluble solid that serves as a buffering agent, emulsifier, and thickening agent in various applications, including food processing and industrial uses.

Chemical Properties

Tetrasodium pyrophosphate is a sodium salt of pyrophosphoric acid. It is composed of four sodium ions and a pyrophosphate anion. The compound is highly soluble in water, forming an alkaline solution. It has a melting point of approximately 988 °C and is stable under normal conditions.

Production

Tetrasodium pyrophosphate is produced by the thermal dehydration of sodium phosphate monobasic or dibasic. The process involves heating the sodium phosphate to remove water, resulting in the formation of the pyrophosphate compound:

2 Na2HPO4 _ Na4P2O7 + H2O

Applications

Food Industry

In the food industry, tetrasodium pyrophosphate is used as an emulsifier and thickening agent. It is commonly found in processed foods such as canned fish, pudding, and marshmallows. It helps to improve the texture and stability of these products. Additionally, it acts as a leavening agent in baking powders.

Industrial Uses

Tetrasodium pyrophosphate is used in various industrial applications. It serves as a detergent and water softener in cleaning products. In metal treatment, it is used for rust removal and as a metal cleaner. It is also employed in ceramics and textile processing.

Dental Care

In oral hygiene products, tetrasodium pyrophosphate is used to control tartar formation. It is a common ingredient in toothpaste and mouthwash, where it helps to prevent the accumulation of dental calculus.

Safety and Handling

Tetrasodium pyrophosphate is generally recognized as safe (GRAS) when used in accordance with good manufacturing practices. However, it should be handled with care, as it can cause irritation to the skin and eyes. Proper protective equipment, such as gloves and goggles, should be worn when handling the compound.

Environmental Impact

As a phosphate compound, tetrasodium pyrophosphate can contribute to eutrophication if released into water bodies in large quantities. It is important to manage its disposal properly to minimize environmental impact.

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Contributors: Prab R. Tumpati, MD