Raman scattering

Raman Scattering, also known as the Raman Effect, is a phenomenon in physics and chemistry where light scatters inelastically off molecules or crystals, causing the energy of the photons to change. This effect was first discovered in 1928 by Indian physicist C. V. Raman and his student K. S. Krishnan. The discovery of Raman Scattering earned C. V. Raman the Nobel Prize in Physics in 1930. This article provides an overview of the principles behind Raman Scattering, its applications, and its significance in various scientific fields.

Principles of Raman Scattering

Raman Scattering occurs when light interacts with the vibrational or rotational energy levels of a molecule. Unlike Rayleigh scattering, which involves elastic scattering of photons, Raman Scattering involves the exchange of energy between the photons and the material, leading to a shift in the energy (and thus the wavelength) of the scattered light. This shift provides information about the vibrational modes of the molecules, making Raman Scattering a powerful tool for molecular identification and characterization.

Stokes and Anti-Stokes Raman Scattering

There are two types of Raman Scattering: Stokes and Anti-Stokes. In Stokes Raman Scattering, the scattered photons have less energy than the incident photons, corresponding to a transfer of energy from the photons to the material. In Anti-Stokes Raman Scattering, the scattered photons have more energy than the incident photons, indicating that the material has transferred energy to the photons. The intensity and frequency shifts in both Stokes and Anti-Stokes scattering provide valuable information about the molecular structure and dynamics.

Applications of Raman Scattering

Raman Scattering has a wide range of applications across various fields:

- Material Science: Used to characterize materials, study crystal structures, and investigate semiconductor properties. - Chemistry: Enables the study of chemical bonds and reactions, and the identification of substances. - Biology: Applied in the study of cells and tissues, including the detection of diseases and the analysis of biochemical processes. - Pharmaceuticals: Used in drug development and quality control. - Environmental Science: Helps in the detection of pollutants and the analysis of atmospheric components.

Raman Spectroscopy

Raman Spectroscopy is the technique used to observe Raman Scattering. It involves illuminating a sample with a monochromatic light source (usually a laser) and measuring the intensity and wavelength of the scattered light. The resulting spectrum, known as a Raman spectrum, provides a unique fingerprint of the molecules present in the sample.

Significance of Raman Scattering

The discovery of Raman Scattering has had a profound impact on scientific research, providing a non-destructive, label-free method for analyzing the composition and structure of materials. Its ability to provide detailed information about molecular vibrations and chemical bonds makes it an indispensable tool in many areas of research and industry.

See Also

• Spectroscopy
• Laser
• Molecular physics
• Chemical physics

References

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  1928 Benzene Raman Spectrum
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  Setup Raman Spectroscopy adapted from Thomas Schmid and Petra Dariz in Heritage 2(2) (2019) 1662-1683
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  Ramanscattering