Gallium(III) fluoride

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Gallium(III) fluoride, also known as gallium trifluoride, is a chemical compound with the formula GaF3. It is a white or colorless solid that is insoluble in water. This compound is of interest in the field of chemistry, particularly in the study of materials and compounds containing gallium.

Properties

Gallium(III) fluoride is characterized by its high melting point and its ability to act as a Lewis acid, making it useful in certain chemical reactions and processes. The compound forms as a white or colorless crystalline solid that is stable under normal conditions but reacts with strong alkali to form gallates.

Synthesis

Gallium(III) fluoride can be synthesized by reacting gallium metal with fluorine gas. The reaction is highly exothermic and must be conducted under controlled conditions to prevent accidents. Another method involves the reaction of gallium(III) oxide with hydrofluoric acid, which also yields gallium(III) fluoride.

Applications

While gallium(III) fluoride is not as widely used as other gallium compounds, it has found applications in the synthesis of organofluorine compounds and in the optical industry due to its low refractive index and high resistance to thermal and chemical damage. It is also used in research settings for the preparation of other gallium-containing compounds.

Safety

Handling of gallium(III) fluoride requires caution. It is harmful if inhaled or ingested, and it can cause irritation to the skin and eyes. Appropriate safety measures, including the use of personal protective equipment, should be taken when working with this compound.

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Contributors: Prab R. Tumpati, MD