Uranium tetrafluoride
Chemical compound
Uranium tetrafluoride (UF4) is an important uranium compound used in the nuclear fuel cycle. It is a green crystalline solid and is one of the intermediate compounds in the conversion of uranium hexafluoride (UF6) to uranium dioxide (UO2) or uranium metal.
Properties
Uranium tetrafluoride is a green, hygroscopic solid. It is less volatile than uranium hexafluoride and is used in the reduction of UF6 to uranium metal. UF4 is soluble in water and reacts with moisture to form hydrofluoric acid.
Production
UF4 is produced by the reaction of uranium dioxide (UO2) with hydrogen fluoride (HF) at elevated temperatures. The reaction is as follows:
- UO2 + 4 HF _ UF4 + 2 H2O
This process is part of the conversion of uranium ore concentrates to UF6 in the nuclear fuel cycle.
Applications
Uranium tetrafluoride is primarily used as an intermediate in the production of uranium metal and uranium hexafluoride. It is also used in the nuclear industry for the preparation of uranium dioxide fuel pellets.
Safety
UF4 is a hazardous material and must be handled with care. It is toxic and poses a risk of radiation exposure due to its uranium content. Proper safety measures, including the use of personal protective equipment and adequate ventilation, are necessary when handling this compound.
Related pages
References

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