Iodic acid: Difference between revisions

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{{Short description|Chemical compound}}
{{DISPLAYTITLE:Iodic acid}}
{{Infobox chemical
[[File:Iodic_acid.svg|thumb|right|150px|Structural formula of iodic acid]]
| verifiedfields = changed
| verifiedrevid = 477002372
| name = Iodic acid
| image = Iodic acid.png
| image2 = Iodic-acid-3D-balls.png
| pin = Iodic acid
| othernames = Hydrogen iodate
| section1 =
| casno = 7782-68-5
| pubchem = 24345
| chemspiderid = 22785
| einecs = 231-969-6
| unii = 8VZV102JFY
| chebi = 24858
| chembl = 1233245
| rtek = NN1575000
| beilstein = 3587200
| gmelin = 2020
| smiles = OI(=O)=O
| inchi = 1S/HIO3/c2-1(3)4/h(H,2,3,4)
| inchikey = ICIWUVCWSCSTAQ-UHFFFAOYSA-N
| section2 =
| formula = HIO_3
| molarmass = 175.91 g/mol
| appearance = White crystals
| density = 4.62 g/cm³
| meltingptc = 110
| boilingptc = 101
| solubility = Soluble in water
| solubility1 = Soluble
| solubility1note = in ethanol
| solubility2 = Insoluble
| solubility2note = in ether
| acidity = 0.75
| conjugatebase = [[Iodate]]
| pka = 0.75
| section3 =
| crystalstruct = Monoclinic
| dipole = 2.13 D
| refractive = 1.8
| section4 =
| ld50 = 505 mg/kg (oral, rat)
| ghssignalword = Danger
| nfpa-h = 3
| nfpa-f = 0
| nfpa-r = 0
| flashpt = Non-flammable
}}


'''Iodic acid''' is a chemical compound with the formula '''HIO_3'''. It is a white crystalline solid and is one of the most important [[oxides of iodine]]. Iodic acid is a strong [[acid]] and is used in various chemical reactions and industrial processes.
'''Iodic acid''' is a chemical compound with the formula '''HIO_'''. It is a white crystalline solid and is one of the most important [[oxides of iodine]]. Iodic acid is a strong [[acid]] and is used in various chemical reactions and industrial applications.


== Chemical Properties ==
==Chemical Properties==
Iodic acid is a strong acid with a pKa of 0.75. It is highly soluble in water and ethanol but insoluble in ether. The compound has a monoclinic crystal structure and a dipole moment of 2.13 D. It decomposes upon heating to produce [[iodine pentoxide]] (I_2O_5) and water.
Iodic acid is a strong acid, comparable in strength to [[sulfuric acid]]. It is highly soluble in water, forming a colorless solution. The acid dissociates in water to form [[hydronium ions]] and iodate ions:


== Synthesis ==
: HIO_ + H_O _ H_O_ + IO__
Iodic acid can be synthesized by the oxidation of [[iodine]] with strong oxidizing agents such as [[nitric acid]] or [[chlorine]] in the presence of water. The reaction is as follows:
<math> I_2 + 5 H_2O + 5 Cl_2 → 2 HIO_3 + 10 HCl </math>


== Uses ==
Iodic acid is a powerful oxidizing agent and can oxidize [[sulfur dioxide]] to [[sulfuric acid]] and [[hydrogen sulfide]] to [[sulfur]].
Iodic acid is used in various applications including:
* As a strong oxidizing agent in chemical reactions.
* In the preparation of [[iodates]], which are used in analytical chemistry.
* In the production of [[disinfectants]] and [[antiseptics]].


== Safety ==
==Preparation==
Iodic acid is classified as a hazardous substance. It is corrosive and can cause severe burns upon contact with skin or eyes. It is also harmful if ingested or inhaled. Proper safety measures should be taken when handling iodic acid, including the use of personal protective equipment.
Iodic acid can be prepared by oxidizing [[iodine]] with strong oxidizing agents such as [[nitric acid]] or [[chlorine]] in the presence of water:


== Related Compounds ==
: I_ + 5 HNO_ _ 2 HIO_ + 5 NO_ + H_O
 
Alternatively, it can be produced by the reaction of [[iodine pentoxide]] with water:
 
: I_O_ + H_O _ 2 HIO_
 
==Uses==
Iodic acid is used in analytical chemistry as a reagent for the determination of [[arsenic]] and [[antimony]]. It is also used in the synthesis of [[iodates]], which are salts of iodic acid. These iodates are used in the food industry as a source of iodine in [[iodized salt]].
 
==Safety==
Iodic acid is a strong oxidizer and should be handled with care. It can cause burns upon contact with skin and is harmful if ingested. Proper safety precautions, including the use of [[personal protective equipment]], should be taken when handling iodic acid.
 
==Related pages==
* [[Iodine]]
* [[Iodine]]
* [[Iodine pentoxide]]
* [[Iodine pentoxide]]
* [[Iodate]]
* [[Iodate]]
* [[Periodic acid]]
* [[Oxidizing agent]]
 
== See Also ==
* [[Oxides of iodine]]
* [[Inorganic acids]]
* [[Oxidizing agents]]
 
== References ==
{{Reflist}}


[[Category:Acids]]
[[Category:Acids]]
[[Category:Iodine compounds]]
[[Category:Oxidizing agents]]
[[Category:Oxidizing agents]]
[[Category:Iodine compounds]]
[[Category:Inorganic compounds]]
{{chemistry-stub}}

Latest revision as of 04:03, 13 February 2025

Structural formula of iodic acid

Iodic acid is a chemical compound with the formula HIO_. It is a white crystalline solid and is one of the most important oxides of iodine. Iodic acid is a strong acid and is used in various chemical reactions and industrial applications.

Chemical Properties[edit]

Iodic acid is a strong acid, comparable in strength to sulfuric acid. It is highly soluble in water, forming a colorless solution. The acid dissociates in water to form hydronium ions and iodate ions:

HIO_ + H_O _ H_O_ + IO__

Iodic acid is a powerful oxidizing agent and can oxidize sulfur dioxide to sulfuric acid and hydrogen sulfide to sulfur.

Preparation[edit]

Iodic acid can be prepared by oxidizing iodine with strong oxidizing agents such as nitric acid or chlorine in the presence of water:

I_ + 5 HNO_ _ 2 HIO_ + 5 NO_ + H_O

Alternatively, it can be produced by the reaction of iodine pentoxide with water:

I_O_ + H_O _ 2 HIO_

Uses[edit]

Iodic acid is used in analytical chemistry as a reagent for the determination of arsenic and antimony. It is also used in the synthesis of iodates, which are salts of iodic acid. These iodates are used in the food industry as a source of iodine in iodized salt.

Safety[edit]

Iodic acid is a strong oxidizer and should be handled with care. It can cause burns upon contact with skin and is harmful if ingested. Proper safety precautions, including the use of personal protective equipment, should be taken when handling iodic acid.

Related pages[edit]