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'''Technetium''' is a [[chemical element]] with the symbol '''Tc''' and atomic number 43. It is the lightest element whose isotopes are all [[radioactive]]; none are stable, excluding the fully ionized state of 97Tc. Nearly all technetium is produced synthetically, and only minute amounts are found in nature. Naturally occurring technetium occurs as a spontaneous fission product in [[uranium]] ore or by neutron capture in [[molybdenum]] ores. The chemical properties of this silvery gray, crystalline transition metal are intermediate between [[rhenium]] and [[manganese]].
{{DISPLAYTITLE:Technetium}}
 
[[File:Periodisches_System_der_Elemente_(1904-1945,_now_Gdansk_University_of_Technology).jpg|thumb|right|Technetium in the periodic table]]
 
'''Technetium''' is a chemical element with the symbol '''Tc''' and atomic number 43. It is the lightest element whose isotopes are all radioactive; none are stable. Nearly all technetium is produced synthetically, and it is primarily used in the field of [[nuclear medicine]].


==History==
==History==
Technetium was formally discovered in 1937 by [[Carlo Perrier]] and [[Emilio Segrè]], who were able to demonstrate that technetium-95 and technetium-97 are produced by the [[neutron]] bombardment of [[molybdenum]]. This was the first element to be artificially produced, hence its name, from the Greek τεχνητός, meaning "artificial".
Technetium was the first element to be artificially produced. It was discovered in 1937 by [[Carlo Perrier]] and [[Emilio Segrè]] in a sample of molybdenum that had been bombarded with deuterons in a cyclotron. The element was named from the Greek word "technetos," meaning "artificial," reflecting its synthetic origin.
 
==Properties==
Technetium is a silvery-gray metal that tarnishes slowly in moist air. It is a member of the [[transition metals]] and is located in group 7 of the periodic table. Technetium is chemically similar to [[rhenium]] and [[manganese]].


==Properties and compounds==
===Isotopes===
Technetium exhibits nine oxidation states from −1 to +7, with +4, +5, and +7 being the most common. Technetium dissolves in [[aqua regia]], [[nitric acid]], and [[concentrated sulfuric acid]], but it is not soluble in [[hydrochloric acid]] of normal strength. This behavior is similar to that of [[rhenium]] and [[manganese]], the elements above and below technetium in the periodic table.
[[File:First_technetium-99m_generator_-_1958.jpg|thumb|left|First technetium-99m generator - 1958]]
The most common isotope of technetium is technetium-99, which is a product of the fission of [[uranium-235]] in nuclear reactors. Technetium-99m, a metastable nuclear isomer, is used in various diagnostic tests in nuclear medicine due to its short half-life of about 6 hours and its ability to emit gamma rays.


==Applications==
==Applications==
The most common use of technetium is in medical imaging. Technetium-99m is used in over 20 million diagnostic nuclear medical procedures annually. Other uses of technetium include the production of [[radioactive tracer]]s and as an industrial gamma ray source.
Technetium is primarily used in [[nuclear medicine]] for diagnostic imaging. The isotope technetium-99m is used in approximately 85% of all diagnostic imaging procedures in nuclear medicine. It is used in [[bone scans]], [[myocardial perfusion imaging]], and other diagnostic tests.
 
[[File:Pertechnetate1.svg|thumb|right|Pertechnetate ion structure]]
 
===Chemical Compounds===
Technetium forms a variety of chemical compounds, including oxides, halides, and complex ions. The pertechnetate ion (TcO₄⁻) is the most stable form of technetium in aqueous solutions and is used in many radiopharmaceuticals.
 
[[File:Chloro-containing_coordination_complexes_of_technetium_(Tc-99).jpg|thumb|left|Chloro-containing coordination complexes of technetium (Tc-99)]]
 
==Production==
Technetium is produced as a byproduct of the fission of uranium-235 in nuclear reactors. It can also be produced by bombarding molybdenum-98 with neutrons. The extraction of technetium from spent nuclear fuel involves complex chemical processes.


==See also==
==Safety==
* [[List of chemical elements]]
Technetium is radioactive, and its handling requires precautions to avoid exposure. The most common isotope, technetium-99, has a half-life of 211,000 years and decays by beta emission. Proper shielding and handling protocols are essential to ensure safety.
 
==Related pages==
* [[Nuclear medicine]]
* [[Radioisotope]]
* [[Periodic table]]
* [[Periodic table]]
* [[Transition metals]]


==References==
[[Category:Transition metals]]
<references />
 
[[Category:Chemical elements]]
[[Category:Chemical elements]]
[[Category:Transition metals]]
[[Category:Nuclear medicine]]
[[Category:Technetium]]
 
{{stub}}
<gallery>
File:Periodisches_System_der_Elemente_(1904-1945,_now_Gdansk_University_of_Technology).jpg|Technetium
File:Pertechnetate1.svg|Pertechnetate ion structure
File:Zirconium-tetrachloride-3D-balls-A.png|Technetium
File:Chloro-containing_coordination_complexes_of_technetium_(Tc-99).jpg|Chloro-containing coordination complexes of technetium (Tc-99)
File:Tc_CNCH2CMe2(OMe)_6Cation.png|Technetium
File:First_technetium-99m_generator_-_1958.jpg|First technetium-99m generator - 1958
File:Basedow-vor-nach-RIT.jpg|Technetium
</gallery>

Latest revision as of 10:55, 23 March 2025


Technetium in the periodic table

Technetium is a chemical element with the symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive; none are stable. Nearly all technetium is produced synthetically, and it is primarily used in the field of nuclear medicine.

History[edit]

Technetium was the first element to be artificially produced. It was discovered in 1937 by Carlo Perrier and Emilio Segrè in a sample of molybdenum that had been bombarded with deuterons in a cyclotron. The element was named from the Greek word "technetos," meaning "artificial," reflecting its synthetic origin.

Properties[edit]

Technetium is a silvery-gray metal that tarnishes slowly in moist air. It is a member of the transition metals and is located in group 7 of the periodic table. Technetium is chemically similar to rhenium and manganese.

Isotopes[edit]

First technetium-99m generator - 1958

The most common isotope of technetium is technetium-99, which is a product of the fission of uranium-235 in nuclear reactors. Technetium-99m, a metastable nuclear isomer, is used in various diagnostic tests in nuclear medicine due to its short half-life of about 6 hours and its ability to emit gamma rays.

Applications[edit]

Technetium is primarily used in nuclear medicine for diagnostic imaging. The isotope technetium-99m is used in approximately 85% of all diagnostic imaging procedures in nuclear medicine. It is used in bone scans, myocardial perfusion imaging, and other diagnostic tests.

Pertechnetate ion structure

Chemical Compounds[edit]

Technetium forms a variety of chemical compounds, including oxides, halides, and complex ions. The pertechnetate ion (TcO₄⁻) is the most stable form of technetium in aqueous solutions and is used in many radiopharmaceuticals.

Chloro-containing coordination complexes of technetium (Tc-99)

Production[edit]

Technetium is produced as a byproduct of the fission of uranium-235 in nuclear reactors. It can also be produced by bombarding molybdenum-98 with neutrons. The extraction of technetium from spent nuclear fuel involves complex chemical processes.

Safety[edit]

Technetium is radioactive, and its handling requires precautions to avoid exposure. The most common isotope, technetium-99, has a half-life of 211,000 years and decays by beta emission. Proper shielding and handling protocols are essential to ensure safety.

Related pages[edit]