Bromobenzyl cyanide

Bromobenzyl cyanide (BBC), also known as CA in military contexts, is a cyanide-based tear gas that was used in World War I for chemical warfare. It is a colorless liquid at room temperature and is considered one of the most potent lacrimators. Bromobenzyl cyanide works by irritating the mucous membranes of the eyes, nose, mouth, and lungs, leading to tearing, sneezing, coughing, and in severe cases, temporary blindness. Its chemical formula is C₈H₆BrN.

History

Bromobenzyl cyanide was first synthesized in the early 20th century. Its use as a chemical weapon was pioneered during World War I, where it was deployed in chemical warfare to incapacitate enemy troops. Despite its effectiveness, the use of bromobenzyl cyanide and similar chemical agents was later restricted under various international treaties, including the Geneva Protocol of 1925, due to their inhumane effects.

Chemical Properties

Bromobenzyl cyanide is an aromatic compound that consists of a benzene ring substituted with a bromine atom and a cyanide group. This structure contributes to its high reactivity and toxicity. It has a boiling point of 242°C and a melting point of 26-27°C. Being less volatile than some other chemical agents, it persists in the environment for longer periods, which can lead to prolonged exposure risks.

Health Effects

Exposure to bromobenzyl cyanide can cause severe irritation to the eyes, skin, and respiratory system. Symptoms of exposure include but are not limited to tearing, redness of the eyes, coughing, difficulty breathing, and skin irritation. In high concentrations, it can cause more severe respiratory distress and even temporary blindness. Immediate decontamination and medical treatment are essential after exposure to mitigate the health effects.

Usage and Regulation

While bromobenzyl cyanide was initially used in military operations, its use has been significantly restricted by international law. The Chemical Weapons Convention (CWC), which came into effect in 1997, prohibits the production, stockpiling, and use of chemical weapons, including bromobenzyl cyanide. Today, research into the effects and countermeasures of chemical agents like BBC continues, primarily for the purpose of defense and protective measures.

Environmental Impact

The environmental impact of bromobenzyl cyanide is notable due to its persistence. It can contaminate soil and water sources, posing risks to wildlife and potentially entering the food chain. Cleanup and decontamination efforts are required to mitigate its environmental effects.

See Also

• Chemical warfare
• Cyanide poisoning
• Geneva Protocol
• Chemical Weapons Convention

References

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Bromobenzyl cyanide

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  2-bromo-2-phenylacetonitrile 2D skeletal structure